Search results for "line shape"
showing 10 items of 13 documents
Diagnostics of Helium-Argon Arc Discharge Plasma Based on Spectral Line Shape Measurements
1999
Electron densities and ion (gas) temperatures on the axis of an arc discharge plasma, produced at atmospheric pressure in a gas mixture of 95% helium and 5% argon, are determined at two arc currents. The evaluation of both main plasma parameters is based on line shape measurements, the ion temperature on the Doppler broadening of selected ArII lines, while the electron density on the Stark broadening of the hydrogen Hp line which appear in the spectrum due to hydrogen traces in the applied gases. The significance of reliable plasma diagnostics for determination of atomic structure data is discussed.
Etude théorique de spectres de molécules toupies sphériques à l'aide du formalisme d'ensembles tensoriels irréductibles
2022
Vibrational-rotational spectroscopy of molecules of the spherical top type, in particular, SiH4 and GeH4 molecules, as well as their isotopologues, is of interest in various fields of science and technology, especially in astrophysics and planetology. One of the most important discoveries in the study of the atmospheres of giant planets is the discovery of german and silane gases in the atmospheres of Saturn, Titan, and Jupiter. Despite many years of research on the vibrational-rotational spectra of molecules of german, silane, and their deuterated modifications, many spectral ranges are still unexplored. However, a complete study of the atmospheres of giant planets is possible only in the …
Diagnostics of capillary light sources by means of line shape measurements and modeling
2012
In this work the Hg visible triplet spectral lines were measured by means of Fourier Transform spectrometer and deconvoluted by Tikhonov's regularisation method and line shape modelling. The lines were collected from Hg/Ar and Hg/Xe high frequency capillary lamps. In our previous work, the spatial plasma homogeneity of isotope Hg/Xe and Hg/Ar capillary lamps was investigated by means of tomography. The lamps were operated in different working positions – horizontally and vertically. In this work the spectral diagnostics of capillary light sources by means of spectral line shape measurements and modelling is presented to obtain plasma temperature. The results are compared with the results fo…
Line Shape Measurement and Modelling for Plasma Diagnostics
2014
In this paper we discuss different methods of narrow spectral line shape measurements for a wide spectral range by means of high-resolution spectrometers such as the Fabry-Perot spectrometer, Zeeman spectrometer and Fourier transform spectrometer as well as a theoretical model for spectral line shape modelling and solving of the inverse task based on Tikhonov's regularization method. Special attention is devoted to the line shape measurements for the optically thin light sources filled with Hg, Ar, Xe, Kr for their use in high precision analysers for detection of heavy metals and benzene.
Study of the far wing of the Balmer α line of hydrogen perturbed by collisions with protons
2002
The theory of the Balmer α line of atomic hydrogen perturbed by collisions with protons predicts quasi-molecular satellites in the line wing due to H-H+ collisions. Measurements of the spectrum of a laser-produced plasma confirm the existence of the strongest of these features.
Deconvolution of the spectral line profiles for the plasma temperature estimation
2010
Abstract The Hg 253.7 nm spectral line profiles, emitted from the mercury–argon high-frequency electrodeless discharge lamps (HFEDL) have been measured by means of a high-resolution scanning Fabry–Perrot interferometer at the mercury cold spot temperature value at 20 °C, different discharge current and buffer gas values. The deconvolution procedure by means of the Tikhonov's regularization method was performed to obtain the real spectral line shape. The influence of the instrumental function and absorption, real width of the Hg 253.7 nm resonance line and temperature of the radiating atoms are obtained. The results were compared with the results of the nonlinear multiparameter mathematical …
Real-time optical spectrum analyzers operating with spectrally incoherent broadband continuous-wave light source
2007
On the framework of coherence theory we discuss the averaged temporal intensity output provided by real-time optical Fourier transformers when the spectral line shape of the stationary source is considered. Some numerical examples are given and the deviations from perfectly monochromatic sources are pointed out.
Optical diagnostic of temperature in rocket engines by coherent Raman techniques
2004
Abstract This article reviews the study of Raman line shapes of molecular species involved in reactive media, such flames or engines, at high temperature and high pressure. This study is of interest from a fundamental as well as from a practical point of view with regards to the CARS temperature diagnostic of GH2–LOX combustion systems. We will particularly draw attention to recent investigations by means of Stimulated Raman Spectroscopy (SRS) in H2–H2O mixtures at temperature up to 1800 K. Whereas H2–X systems usually exhibit large inhomogeneous effects, due to the speed dependence of the collisional parameters, the absence of such apparent inhomogeneous signatures in the H2–H2O system all…
<title>Deconvolution of the mercury 253.7 nm spectral line shape for the use in absorption spectroscopy</title>
2008
In this work we present measurement and results of the deconvolution of the Hg 253.7 nm spectral line shapes, emitted from the mercury isotope high-frequency electrodeless discharge lamps, made at the Institute of Atomic Physics and Spectroscopy for the use in Zeeman Atomic Absorption Spectrometry. The emission line profiles of 254 nm Hg resonance line have been measured by means of a Zeeman scanning spectrometer at the mercury cold spot temperature value at 20 C. Then the deconvolution procedure or solving of this ill-posed inverse problem by means of the Tikhonov's regularization method [1] was performed to obtain the real spectral line shape.© (2008) COPYRIGHT SPIE--The International Soc…
Inhomogeneous speed effects on H-2 vibrational line profiles in ternary mixtures
2000
International audience; A study of speed inhomogeneous broadening of the hydrogen vibrational line profiles in the collisional regime for ternary mixtures is reported. The Q(1) line of H-2 in H-2-Ar-N-2, H-2-He-Ar, and H-2-He-N-2 mixtures is investigated by high resolution stimulated Raman spectroscopy for various concentrations and temperatures. A model, successfully used for binary mixtures, is extended to ternary mixtures. An excellent agreement is obtained between theory and experiment for H-2-Ar-N-2, by using the collisional parameters previously obtained from binary mixtures study. For H-2-He-Ar and H-2-He-N-2, H-2-He collisions play a "hardening" effect in the H-2 soft speed memory m…